Yes. PIP is not means-tested, so being unemployed does not by itself make you eligible or ineligible; the decision is based on how a long-term health condition or disability affects daily living and mobility activities. You may need to explain your difficulties at an assessment and provide supporting evidence, such as medical or care records, where available. PIP is separate from Universal Credit’s work capability assessment, so check the relevant GOV.UK guidance for both claims and report any changes in your circumstances.