Yes. You do not need to be employed to claim Child Benefit, provided you are responsible for a child under 16, or under 20 if they remain in approved education or training. Usually, only one person can claim for each child, and the child must normally live with you or you must contribute towards their upkeep. Child Benefit can also provide National Insurance credits towards your State Pension, which may be useful if you are not working. Check the latest rules and apply through GOV.UK; a high-income charge may apply if you or your partner’s income is over the relevant threshold.